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Mass spectrometry is more often applied to molecules than to atoms. We will see in Chapter that the molecular weight of a molecule is the sum of the atomic weights of the atoms in the molecule. The mass spectrum of H is taken under conditions that prevent decomposition into H atoms. The two naturally occurring isotopes of hydrogen are H (atomic mass = 1.00783 amu; abundance 99.9885%) and H (atomic mass = 2.01410 amu; abundance 0.0115%). How many peaks will the mass spectrum have? Give the relative atomic masses of each of these peaks. (c) Which peak will be the largest, and which the smallest?

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Answer:

See explanation

Explanation:

There will be three peaks. The relative masses of each of the peaks is shown below;

1H - 1H peak will have a mass of 2*1.00783 amu = 2.01566 amu

1H -2H peak will have a mass of 1.00783 amu + 2.01410 amu = 3.02193 amu

2H - 2H peak will have a mass of 2*2.01410 amu = 4.0282 amu

The 2H - 2H peak is the smallest while 1H - 1H peak is the largest.