Answer : The molecular weight of a substance is 157.3 g/mol
Explanation :
As we are given that 7 % by weight that means 7 grams of solute present in 100 grams of solution.
Mass of solute = 7 g
Mass of solution = 100 g
Mass of solvent = 100 - 7 = 93 g
Formula used :
[tex]\Delta T_f=i\times K_f\times m\\\\T_f^o-T_f=k_f\times\frac{\text{Mass of substance(solute)}\times 1000}{\text{Molar mass of substance(solute)}\times \text{Mass of water(solvent)}}[/tex]
where,
[tex]\Delta T_f[/tex] = change in freezing point
[tex]T_f^o[/tex] = temperature of pure water = [tex]0^oC[/tex]
[tex]T_f[/tex] = temperature of solution = [tex]-0.89^oC[/tex]
[tex]K_f[/tex] = freezing point constant of water = [tex]1.86^oC/m[/tex]
m = molality
Now put all the given values in this formula, we get
[tex](0-(-0.89))^oC=1.86^oC/m\times \frac{7g\times 1000}{\text{Molar mass of substance(solute)}\times 93g}[/tex]
[tex]\text{Molar mass of substance(solute)}=157.3g/mol[/tex]
Therefore, the molecular weight of a substance is 157.3 g/mol