The solution is found using chemistry techniques.
moles NaOH = c · V = 0.1953 mmol/mL · 18.45 mL = 3.603285 mmol
moles H2SO4 = 3.603285 mmol NaOH · 1 mmol H2SO4 / 2 mmol NaOH = 1.8016425 mmol
Hence
[H2SO4]= n/V = 1.8016425 mmol / 21.25 mL = 0.08478 M
The answer to this question is [H2SO4] = 0.08478 M